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Strong and Weak Acids

Many strategies can be used to differentiate between strong and weak acids. Here are some methods:

  • React with a metal; there would be a greater release of hydrogen gas for stronger acids
  • Test for pH; pH would be lower for stronger acids
  • Test electrical conductivity; would be higher for stronger acids

These results are due to the fact that stronger acids are more reactive, and ionize completely in solution (more H+ ions in solution).

However, in this case, we can look at the bond enthalpies for each compound to determine the weakest acid.

  • Bond enthalpies tell us how much energy is required to break 1 mol of a gaseous covalent bond in a molecule. It is a measure of bond strength.
  • The weaker the acid, the greater the bond enthalpy. This is because a strong bond enthalpy will inhibit the ionization of the acid to produce H+ ions, and so it dissociates partially.

Answer

Looking at tabulated data, we can determine that HF has the greatest bond enthalpy of the options. Therefore, HF must be the weakest acid.

It can be useful to memorize common strong acids to face these kinds of questions. These include:

  • HCl
  • HI
  • HBr
  • HNO3
  • H2SO4
  • HClO4