The location of electrons is described by the electron-pair geometry, and the location of atoms is described by the molecular structure.
Electron-pair geometry is the configuration of all electron density zones around a core atom (bonds, lone pairs, or unpaired electrons). It is the arrangement of electron pairs surrounding a main atom.
The molecular structure of a molecule is made up of the way its atoms are arranged. It refers to how the atoms of a molecule are arranged, usually in reference to one central atom.
The electron-pair geometries will match the molecular structures when there are no lone pairs of electrons surrounding the centre atom, but they will differ if there are lone pairs present.
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