To begin calculating, there is one thing you need to remember :[tex]1 mole of H2O2=34.0148 g[/tex]
Then we have [tex]5.00g of H2O2=5/34.0148=0.146995[/tex]
As you know decomposition of 2moles now has prodused 196kj
So, q is made due [tex]0.146995 moles of H2O2[/tex][tex]=(-196/2)*0.146995=-14.40551Kj[/tex]
I'm sure it will help.