Respuesta :
Answer:
Explanation:
Given data:
A) Volume of CO₂ = 0.100 L
Pressure = 307 torr
Temperature = 26°C
Mass of CO₂ = ?
Solution:
PV = nRT
P= Pressure
V = volume
n = number of moles
R = general gas constant = 0.0821 atm.L/ mol.K
T = temperature in kelvin
Now we will convert the temperature.
26+273 = 299 K
307 torr/760 = 0.40 atm
0.40 atm × 0.100 L = n × 0.0821 atm.L/ mol.K × 299 K
0.04 atm.L = n × 24.55 atm.L/ mol
n = 0.04 atm.L / 24.55 atm.L/ mol
n = 0.002 mol
Mass of CO₂:
Mass = number of moles × molar mass
Mass = 0.002 mol × 44 g/mol
Mass = 0.088 g
Given data:
b) Volume of C₂H₄ = 8.75 L
Pressure = 378.3 Kpa
Temperature = 483 K
Mass of C₂H₄ = ?
Solution:
PV = nRT
P= Pressure
V = volume
n = number of moles
R = general gas constant = 0.0821 atm.L/ mol.K
T = temperature in kelvin
378.3KPa/101 = 3.73 atm
by putting values
3.73 atm × 8.75 L = n × 0.0821 atm.L/ mol.K × 483 K
32.64 atm.L = n × 39.65 atm.L/ mol
n = 32.64 atm.L / 24.55 atm.L/ mol
n = 0.82 mol
Mass of C₂H₄ :
Mass = number of moles × molar mass
Mass = 0.82 mol × 28 g/mol
Mass = 22.96 g
c)
Given data:
A) Volume of Ar = 221 mL
Pressure = 0.23 torr
Temperature = -54°C
Mass of Ar = ?
Solution:
PV = nRT
P= Pressure
V = volume
n = number of moles
R = general gas constant = 0.0821 atm.L/ mol.K
T = temperature in kelvin
Now we will convert the temperature.
-54+273 = 219 K
0.23 torr/760 = 0.0003 atm
221 mL/1000 = 0.221 L
0.0003 atm × 0.221 L = n × 0.0821 atm.L/ mol.K × 219 K
6.63×10⁻⁵ atm.L = n × 17.98 atm.L/ mol
n = 6.63×10⁻⁵ atm.L / 17.98 atm.L/ mol
n = 0.37×10⁻⁵ mol
Mass of Ar:
Mass = number of moles × molar mass
Mass = 0.37×10⁻⁵ mol × 39.9 g/mol
Mass = 14.76 ×10⁻⁵g
The number of moles the gas can be used to calculate the mass of the gas in each case.
Using;
a) PV = nRT
P = 307 torr or 0.4 atm
T = 26 °C + 273 = 299 K
V = 0.100 L
R = 0.082 atm LK-1mol-1
n = PV/RT
n = 0.4 atm × 0.100 L / 0.082 atm LK-1mol-1 × 299 K
n = 0.00163 moles
Mass of CO2 = 0.00163 moles × 44 g/mol = 0.072 g
b) Again;
P = 378.3 kPa or 3.75atm
T = 483 K
V = 8.75 L
R = 0.082 atm LK-1mol-1
n = PV/RT
n = 3.75atm × 8.75 L/0.082 atm LK-1mol-1 × 483 K
n = 0.83 moles
Mass of C2H4 = 0.83 moles × 28 g/mol = 23.24 g
c) Again;
P = 0.23 torr or 0.0003 atm
V = 221 mL or 0.221 L
T = -54 °C + 273 = 219 K
R = 0.082 atm LK-1mol-1
n = PV/RT
n = 0.0003 atm × 0.221 L/0.082 atm LK-1mol-1 × 219 K
n = 3.69 × 10^-6 moles
Mass of Ar = 3.69 × 10^-6 moles × 40 g/mol
Mass of Ar = 1.48 × 10^-4 g
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