Multiples of 3 are: 3, 6, 9, 12, 15, 18, 21, 24, 27, 30, 33, 36, 39, 42, 45, 48, ...
The two digit numbers in that list above all have their digits adding to some other multiple of 3
and so on.
Therefore, the rule is: If the digits add to a multiple of 3, then the original number is a multiple of 3.