Answer:
Endothermic
4.433kJ
15.91 kJ / mol
Explanation:
In water, ammonium chloride dissolves thus:
NH₄Cl(s) → NH₄⁺(aq) + Cl⁻(aq)
As the student observed the temperature decreased, the reaction is endothermic because absorbs heat from surroundigns when occurs.
It is possible to find the absorbed heat using coffee cup calorimeter equation:
Q = m×C×ΔT
Where Q is heat, m is mass of solution (250g + 14.9g = 264.9g), C is specific heat of solution (It is possible to assume specific heat of pure water, 4.184J/g°C), and ΔT is change in temperature (20.0°C-16.0°C = 4.0°C)
Replacing:
Q = 264.9g×4.184J/g°C×4.0°C
Q = 4433 J = 4.433kJ
As enthalpy is the change in heat per mole of reaction, moles of ammonium chloride that reacted were:
14.9g NH₄Cl × (1mol / 53.491g) = 0.2786 moles
As heat produced per 0.2786moles were 4.433kJ, heat per mole of ammonium chloride is:
4.433kJ / 0.2786mol = 15.91 kJ / mol