A 0.600 g sample of diprotic acid H2X is dissolved in water, and titrated to the equivalence point with 40.0 mL of 0.200 M NaOH. Assume both protons of the acid were titrated. What is the molar mass of H2X

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Answer:

150 g/mol

Explanation:

Let's consider the complete neutralization of a diprotic acid H₂X with NaOH.

H₂X + 2 NaOH → Na₂X + 2 H₂O

40.0 mL of 0.200 M NaOH. were required to reach the endpoint. The reacting moles of NaOH are:

0.0400 L × 0.200 mol/L = 8.00 × 10⁻³ mol

The molar ratio of H₂X to NaOH is 1:2. The reacting moles of H₂X are 1/2 × 8.00 × 10⁻³ mol = 4.00 × 10⁻³ mol.

4.00 × 10⁻³ moles of H₂X have a mass of 0.600 g. The molar mass of H₂X is:

0.600 g/4.00 × 10⁻³ mol = 150 g/mol

The molar mass of 0.6 g sample of the diprotic acid, H₂X which reacted with 40 mL of 0.2 M NaOH to the equivalence point is 150 g/mol

We'll begin by calculating the number of mole of NaOH in the solution.

Volume = 40 mL = 40 / 1000 = 0.04 L

Molarity of NaOH = 0.2 M

Mole of NaOH =?

Mole = Molarity x Volume

Mole of NaOH = 0.2 × 0.04

Mole of NaOH = 0.008 mole

  • Next, we shall determine the number of mole of H₂X that will react with 0.008 mole of NaOH to the equivalence point.

H₂X + 2NaOH → Na₂X + 2H₂O

From the balanced equation above,

2 moles of NaOH reacted with 1 mole of H₂X.

Therefore,

0.008 mole of NaOH will react with = 0.008 / 2 = 0.004 mole of H₂X.

  • Finally, we shall determine the molar mass of H₂X.

Mole of H₂X = 0.004 mole

Mass of H₂X = 0.6 g

Molar mass of H₂X =?

Molar mass = mass / mole

Molar mass of H₂X = 0.6 / 0.004

Molar mass of H₂X = 150 g/mol

Therefore, the molar mass of the diprotic acid, H₂X is 150 g/mol

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