Respuesta :
Answer:
P = 17.9618 atm
Explanation:
The osmotic pressure can be calculated and treated as if we are talking about an ideal gas, and it's expression is the same:
pV = nRT
However the difference, is that instead of using moles, it use concentration so:
p = nRT/V ----> but M = n/V so
p = MRT
We have the temperature of 18 °C (K = 18+273.15 = 291.15 K) the value of R = 0.08206 L atm / K mol, so we need to calculate the concentration, and we have the mass of HCl, so we use the molar mass of HCl which is 36.45 g/mol:
n = 13.7/36.45 = 0.3759 moles
M = 0.3759/0.5 = 0.7518 M
Now that we have the concentration, let's solve for the osmotic pressure:
p = 0.7518 * 0.08206 * 291.15
p = 17.9618 atm
The osmotic pressure of the solution is 35.82 atm.
We'll begin by calculating the number of mole of HCl.
- Mass = 13.7 g
- Molar mass of HCl = 1 + 35.5 = 36.5 g/mol
- Mole of HCl =?
Mole = mass / molar mass
Mole of HCl = 13.7 / 36.5
Mole of HCl = 0.375 mole
Next, we shall determine the molarity of the HCl solution.
- Mole of HCl = 0.375 mole
- Volume = 0.5 L
- Molarity of HCl =?
Molarity = mole / Volume
Molarity of HCl = 0.375 / 0.5
Molarity of HCl = 0.75 M
Finally, we shall determine the osmotic pressure of the solution.
- Molarity (M) = 0.75 M
- Temperature (T) = 18 °C = 18 + 273 = 291 K
- Van't Hoff's factor (i) = 2 (electrolyte)
- Gas constant (R) = 0.08206 atm.L/Kmol
- Osmotic pressure (π) =?
π = iMRT
π = 2 × 0.75 × 0.08206 × 291
π = 35.82 atm
Therefore, the osmotic pressure of the solution is 35.82 atm
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