An atom of carbon has a radius of 67.0 pm and the average orbital speed of the electrons in it is about 1.3 x 10⁶ m/s.
Calculate the least possible uncertainty in a measurement of the speed of an electron in an atom of carbon. Write your answer as a percentage of the average speed, and round it to significant digits.

Respuesta :

Answer :

The least possible uncertainty in an electron's velocity is, [tex]4.32\times 10^{5}m/s[/tex]

The percentage of the average speed is, 33 %

Explanation :

According to the Heisenberg's uncertainty principle,

[tex]\Delta x\times \Delta p=\frac{h}{4\pi}[/tex] ...........(1)

where,

[tex]\Delta x[/tex] = uncertainty in position

[tex]\Delta p[/tex] = uncertainty in momentum

h = Planck's constant

And as we know that the momentum is the product of mass and velocity of an object.

[tex]p=m\times v[/tex]

or,

[tex]\Delta p=m\times \Delta v[/tex]      .......(2)

Equating 1 and 2, we get:

[tex]\Delta x\times m\times \Delta v=\frac{h}{4\pi}[/tex]

[tex]\Delta v=\frac{h}{4\pi \Delta x\times m}[/tex]

Given:

m = mass of electron = [tex]9.11\times 10^{-31}kg[/tex]

h = Planck's constant = [tex]6.626\times 10^{-34}Js[/tex]

radius of atom = [tex]67.0pm=67.0\times 10^{-12}m[/tex]     [tex](1pm=10^{-12}m)[/tex]

[tex]\Delta x[/tex] = diameter of atom = [tex]2\times 67.0\times 10^{-12}m=134.0\times 10^{-12}m[/tex]

Now put all the given values in the above formula, we get:

[tex]\Delta v=\frac{6.626\times 10^{-34}Js}{4\times 3.14\times (134.0\times 10^{-12}m)\times (9.11\times 10^{-31}kg)}[/tex]

[tex]\Delta v=4.32\times 10^{5}m/s[/tex]

The minimum uncertainty in an electron's velocity is, [tex]4.32\times 10^{5}m/s[/tex]

Now we have to calculate the percentage of the average speed.

Percentage of average speed = [tex]\frac{\text{Uncertainty in speed}}{\text{Average speed}}\times 100[/tex]

Uncertainty in speed = [tex]4.32\times 10^{5}m/s[/tex]

Average speed = [tex]1.3\times 10^{6}m/s[/tex]

Percentage of average speed = [tex]\frac{4.32\times 10^{5}m/s}{1.3\times 10^{6}m/s}\times 100[/tex]

Percentage of average speed = 33.2 % ≈ 33 %

Thus, the percentage of the average speed is, 33 %