For a certain reaction, the activation energy is 52.1 kJ/mole. By what ratio will the rate constant change if the temperature is decreased from 175C to 75C?

Respuesta :

Answer:

The value of the ratio of the rate constant is [tex]4.02\times10^{-3}[/tex]

Explanation:

Given that,

Energy = 52.1 kJ/mole

Initial temperature = 175°C

Final temperature = 75°C

We need to calculate the ratio of the rate constant change

Using formula of rate constant

[tex]\dfrac{k_{2}}{k_{1}}=\dfrac{E}{R}(\dfrac{1}{T_{2}}-\dfrac{1}{T_{1}})[/tex]

Where. T₁= initial temperature

T₂ = final temperature

E = energy

R = gas constant

Put the value into the formula

[tex]\dfrac{k_{2}}{k_{1}}=\dfrac{52.1}{8.31}(\dfrac{1}{273+75}-\dfrac{1}{273+175})[/tex]

[tex]\dfrac{k_{2}}{k_{1}}=0.00402[/tex]

[tex]\dfrac{k_{2}}{k_{1}}=4.02\times10^{-3}[/tex]

Hence, The value of the ratio of the rate constant is [tex]4.02\times10^{-3}[/tex]