What is the percent yield of CuS for the following reaction given that you start with 15.5 g of Na2S and 12.1 g CuSO4? The actually amount of CuS produced was 3.05 g. Reaction: Na2S + CuSO4 → Na2SO4 + CuS (A) 16.1% (B) 42.1% (C) 18.93% (D) 7.25% (E) not enough information

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Answer:

(B) 42.1%

Explanation:

The formula for the calculation of moles is shown below:

[tex]moles = \frac{Mass\ taken}{Molar\ mass}[/tex]

Given: For [tex]Na_2S[/tex]

Given mass = 15.5 g

Molar mass of [tex]Na_2S[/tex] = 78.0452 g/mol

Moles of [tex]Na_2S[/tex] = 15.5 g / 78.0452 g/mol = 0.1986 moles

Given: For [tex]CuSO_4[/tex]

Given mass = 12.1 g

Molar mass of [tex]CuSO_4[/tex] = 159.609 g/mol

Moles of [tex]CuSO_4[/tex] = 12.1 g / 159.609 g/mol = 0.0758 moles

According to the given reaction:

[tex]Na_2S+CuSO_4\rightarrow Na_2SO_4+CuS[/tex]

1 mole of [tex]Na_2S[/tex] react with 1 mole of [tex]CuSO_4[/tex]

0.1986 mole of [tex]Na_2S[/tex] react with 0.1986 mole of [tex]CuSO_4[/tex]

Available moles of [tex]CuSO_4[/tex] = 0.0758 moles

Limiting reagent is the one which is present in small amount. Thus, [tex]CuSO_4[/tex] is limiting reagent. (0.0758 < 0.1986)

The formation of the product is governed by the limiting reagent. So,

1 mole of [tex]CuSO_4[/tex] gives 1 mole of [tex]CuS[/tex]

0.0758 mole of [tex]CuSO_4[/tex] gives 0.0758 mole of [tex]CuS[/tex]

Molar mass of [tex]CuS[/tex] = 95.611 g/mol

Mass of [tex]CuS[/tex] = Moles × Molar mass = 0.0758 × 95.611 g = 7.2473 g

Theoretical yield = 7.2473 g

Given experimental yield = 3.05 g

% yield = (Experimental yield / Theoretical yield) × 100 = (3.05/7.2473) × 100 = 42.1 %

Option B is correct.

From the information provided, the percent yield of the reaction is 42.1% .

What is percent yield?

The percent yield is the ratio  of the actual yied to the theoretical yield multiplied by 100. We have the reaction;  Na2S + CuSO4 → Na2SO4 + CuS

Number of moles of Na2S  =  15.5 g /78 g/mol = 0.199 moles

Number of moles of CuSO4 = 12.1 g/160 g/mol = 0.076 moles

Since the reaction is 1:1, CUSO4 is the limiting reactant.

1 mole of CUSO4  yields 1 mole of CuS

0.076 moles of  CUSO4  yields 0.076 moles CuS

Mass of CuS = 0.076 moles * 96 g/mol = 7.3 g

Percent yield = 3.05 g/7.3 g * 100 = 42.1%

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