The Ksp for CaCO3 is 3.8 x 10-9. Determine the concentration in moles/liter of calcium ion in a saturated solution of calcium carbonate. a. 3.8 x 10-9 b. 1.4 x 10-17 C. 6.2 x 10-5 d. 6.1 x 10-9

Respuesta :

Answer: c. [tex]6.2\times 10^{-5}moles/L[/tex]

Explanation:

Solubility product is defined as the equilibrium constant in which a solid ionic compound is dissolved to produce its ions in solution. It is represented as [tex]K_{sp}[/tex]

The equation for the ionization of the calcium carbonate is given as:

[tex]CaCO_3\leftrightharpoons Ca^{2+}+CO_3^{2-}[/tex]

We are given:

[tex]K_{sp}=3.8\times 10^{-9}[/tex]

By stoichiometry of the reaction:

1 mole of [tex]CaCO_3[/tex] gives 1 mole of [tex]Ca^{2+}[/tex] and 1 mole of [tex]CO_3^{2-}[/tex].

Expression for the equilibrium constant of [tex]CaCO_3[/tex] will be:

[tex]K_{sp}=[Ca^{2+}][CO_3^{2-}][/tex]

[tex]3.8\times 10^{-9}=[s][s][/tex]

[tex]3.8\times 10^{-9}=s^2[/tex]

[tex]s=6.2\times 10^{-5}moles/L[/tex]

Hence, the concentration in moles/liter of calcium ion in a saturated solution of calcium carbonate is [tex]6.2\times 10^{-5}moles/L[/tex]