Respuesta :

Explanation:

Relation between [tex]pK_{a}[/tex] and [tex]pK_{b}[/tex] is as follows.

                          [tex]pK_{a} + pK_{b}[/tex] = 14

Hence, putting the given values of [tex]pK_{a}[/tex] in order to calculate the value of [tex]pK_{b}[/tex] as follows.

 For [tex]CH_{3}NH^{+}_{3}[/tex] : [tex]pK_{a} + pK_{b}[/tex] = 14

                       10.6 + [tex]pK_{b}[/tex] = 14

                           [tex]pK_{b}[/tex] = 14 - 10.6

                                         = 3.4

For [tex](CH_{3})_{2}NH^{+}_{2}[/tex] : [tex]pK_{a} + pK_{b}[/tex] = 14

                           10.7 + [tex]pK_{b}[/tex] = 14

                           [tex]pK_{b}[/tex] = 14 - 10.7

                                         = 3.3

Hence, smaller is the value of [tex]pK_{b}[/tex] of a specie more will be the value of its [tex]K_{b}[/tex]. Therefore, stronger will be the base.

Thus, we can conclude that [tex](CH_{3})_{2}NH^{+}_{2}[/tex] will be the stronger base.